(3rd Edition) Thomas Engel, Philip Reid-Thermodynamics, Statistical Thermodynamics, & Kinetics-Prentice Hall (2012).pdf

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(3rd Edition) Thomas Engel, Philip Reid-Thermodynamics, Statistical Thermodynamics, & Kinetics-Prentice Hall (2012).pdf
  THIRD EDITION Thomas Engel University of Washington Philip Reid University of Washington Thermodynamics,StatisticalThermodynamics,& Kinetics   Editor in Chief: Adam Jaworski  Executive Editor: Jeanne Zalesky Senior Marketing Manager: Jonathan Cottrell  Associate Editor: Jessica Neumann VP/Executive Director, Development: Carol Trueheart  Development Editor: Michael Sypes  Editorial Assistant: Lisa Tarabokjia  Marketing Assistant: Nicola Houston  Managing Editor, Chemistry and Geosciences: Gina M. Cheselka Senior Project Manager, Production: Beth Sweeten  Associate Media Producer: Ashley Eklund Full Service/Compositor: GEX Publishing Services Senior Technical Art Specialist: Connie Long  Illustrator: Imagineering Media Services, Inc.  Design Manager: Mark Ong  Interior Designer: Integra Software Services, Inc. Cover Designer: BigWig Designs Photo Manager and Researcher: Maya Melenchuk  Text Permissions Manager: Beth Wollar Text Permissions Researcher: Beth Keister Operations Specialist: Jeff SargentCover Photo Credit: Artwork courtesy of Kim Kopp; photo credit: Frank Huster.Credits and acknowledgments borrowed from other sources and reproduced, with permission, in thistextbook appear on the appropriate page within the text or on p. 607.Copyright ©2013, 2010, 2006 Pearson Education, Inc. All rights reserved. Manufactured in the UnitedStates of America. This publication is protected by Copyright, and permission should be obtained from thepublisher prior to any prohibited reproduction, storage in a retrieval system, or transmission in any form orby any means, electronic, mechanical, photocopying, recording, or likewise. To obtain permission(s) to usematerial from this work, please submit a written request to Pearson Education, Inc., PermissionsDepartment, 1900 E. Lake Ave., Glenview, IL 60025. For information regarding permissions, call (847) 486-2635.Many of the designations used by manufacturers and sellers to distinguish their products are claimed astrademarks. Where those designations appear in this book, and the publisher was aware of a trademark claim, the designations have been printed in initial caps or all caps. Library of Congress Cataloging-in-Publication Data Engel, ThomasThermodynamics, statistical thermodynamics, and kinetics / Thomas Engel, Philip Reid. -- 3rd ed.p. cm.Includes index.ISBN 978-0-321-76618-2 (casebound)1. Statistical thermodynamics. 2. Thermodynamics. I. Reid, Philip. II. Title. QC311.5.E65 2013536'.7--dc2320110469101 2 3 4 5 6 7 8 9 10— CRK—15 14 13 12 11ISBN-10:0-321-76618-0; ISBN-13:978-0-321-76618-2www.pearsonhighered.com  To Walter and Juliane, my first teachers, and to Gloria, Alex, and Gabrielle. Thomas Engel To my family. Philip Reid   Brief Contents 1 Fundamental Concepts of Thermodynamics1 2 Heat, Work, Internal Energy, Enthalpy, and theFirst Law of Thermodynamics17 3 The Importance of State Functions: InternalEnergy and Enthalpy45 4 Thermochemistry67 5 Entropy and the Second and Third Laws of Thermodynamics85 6 Chemical Equilibrium125 7 The Properties of Real Gases165 8 Phase Diagrams and the Relative Stability of Solids, Liquids, and Gases181 9 Ideal and Real Solutions209 10 Electrolyte Solutions243 11 Electrochemical Cells, Batteries, and FuelCells259 12 Probability293 13 The Boltzmann Distribution317 14 Ensemble and Molecular Partition Functions339 15 Statistical Thermodynamics371 16 Kinetic Theory of Gases403 17 Transport Phenomena423 18 Elementary Chemical Kinetics455 19 Complex Reaction Mechanisms501 APPENDIX  A Data Tables553 APPENDIX  B Math Supplement571 APPENDIX C Answers to Selected End-of-ChapterProblems 593 CREDITS 607 INDEX 609 iv
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